E-lesson

Unlocked by Ergon: Insulating liquids testing – lesson #9: Oil Acidity Measurement (TAN / Neutralisation Number

Improving the efficiency invests on dissolved gas analysis, planning synchronizing and selecting most adequate paths for the DGA tests

Master’s level Free Monday, 29 June 2026, 1:00 PM TZ Europe/Zagreb
Free Master’s level

Hosted by: Marius Grisaru / Master's level

Key focus

To understand what acidity measurements represent, how they are obtained, and how they should be interpreted in the context of transformer ageing.

Lesson description

This lesson examines acidity measurements (TAN) as an indicator of oil oxidation and ageing. It explains how acids form through oxidation in mineral oils and through hydrolysis processes in ester liquids, and why not all acids have the same significance.

The lesson reviews the main analytical methods used to determine acidity, including indicator titration, potentiometric titration, and spectroscopic estimation. It also explains how acidity relates to sludge formation, paper ageing, inhibitor depletion, and oil treatment requirements.

Practical interpretation strategies are emphasised, highlighting the need to assess acidity together with other parameters such as inhibitor condition, moisture content, interfacial tension, and oxidation stability.

Learning outcomes

  • Explain what TAN represents and why acidity is an important ageing indicator.
  • Distinguish between different types of organic acids and their impact on insulation systems.
  • Compare common acidity test methods and understand their limitations.
  • Recognise how acidity relates to oxidation, sludge formation, and treatment need.
  • Interpret acidity together with other oil parameters for sound maintenance decisions.

 

Content of this lesson is fully vendor agnostic but it is sponsored by Ergon!

 

 

 

About the author

Marius Grisaru

Marius Grisaru

The author – Marius Grisaru is a chemist with expertise in the insulating oil domain, focusing on oil test procedures from sampling to diagnosing. Marius has vast and worldwide experience on sampling, testing, ordering, diagnosing, and debating among fellow experts around the globe.